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[ 491EMATCSMV19 ] VL (*)(Catalytic) Activation of Small Molecules
Versionsauswahl
(*) Leider ist diese Information in Deutsch nicht verfügbar.
Workload Ausbildungslevel Studienfachbereich VerantwortlicheR Semesterstunden Anbietende Uni
3 ECTS M1 - Master 1. Jahr Chemie Christoph Topf 2 SSt Johannes Kepler Universität Linz
Detailinformationen
Quellcurriculum Masterstudium Chemistry and Chemical Technology 2025W
Lernergebnisse
Kompetenzen
(*)The lecture conveys guiding principles that allow the students to draw analogies between natural metalloenzymes and simple metal complexes based on non-noble metals. This ability eventually allows for the rational design of base metal catalysts that mimic the reactivity of several important cofactors that occur in nature. These model compounds have the potential to outperform existing catalysts that are mostly based on scarce and expensive precious metals.
Fertigkeiten Kenntnisse
(*)The contents of the course will enable students to gain insight into • synthesis and characterization of privileged ligand platforms and bio-inspired base metal complexes (k1, k2, k3) • applications of rational guidelines for the cleavage of strong bonds in common small molecules to convert them into value-added chemicals (k3, k4, k5, k6) • learn how to store gaseous hydrogen and carbon dioxide in a chemical bond to establish a prospective hydrogen or methanol economy (k3, k4, k5) (*)• Catalytic cleavage of the following molecules is discussed in detail: - Hydrogen - Nitrogen - Carbon monoxide - Methane and related alkanes; - Carbon monoxide - Oxygen - Carbon dioxide

• Oxygen transport and storage with biological iron- and copper-based enzymes

Beurteilungskriterien (*)Written examination at the end of the semester
Lehrmethoden (*)Power Point presentation
Abhaltungssprache Englisch
Literatur (*)- Organometallic Chemistry, 3rd Ed.; G. O. Spessard, G. L. Messler, 2016, Oxford University Press.
- Bioinspired Catalysis, W. Weigand, P. Schollhammer, 2016, Wiley-VCH.
- Activation of Small Molecules; W. B. Tolman (Eds), 2006, Wiley-VCH.
Lehrinhalte wechselnd? Nein
Frühere Varianten Decken ebenfalls die Anforderungen des Curriculums ab (von - bis)
491WANCKAMV16: VL (Katalytische) Aktivierung kleiner Moleküle (2016W-2019S)
Präsenzlehrveranstaltung
Teilungsziffer -
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