 |
| Detailinformationen |
| Quellcurriculum |
Masterstudium Chemistry and Chemical Technology 2025W |
| Lernergebnisse |
Kompetenzen |
| (*)The lecture on Organometallic Chemistry is focusing on the chemistry of compounds containing transition metal-carbon bounds and their application in organic synthesis and modern catalytic processes. The lecture features the basic concepts of transition metal chemistry and the synthesis of a wide variety of compounds and complexes. Beside the chemistry of transition metals also element-organic chemistry of the main group elements will be discussed where appropriate and comparisons drawn between elements and groups. Important concepts like the isolobal concept, cluster chemistry, bonding models, organometallic photochemistry, sustainability of transition metal chemistry, etc. will be discussed as well.
|
|
| Fertigkeiten |
Kenntnisse |
| (*)The contents of the course will enable students to
• define, rememorize and understand basic and advanced concepts of inorganic and organometallic chemistry. (k1, k2, k4)
• apply concepts like electron-counting or the isolobal concept to organometallic compounds. (k2, k4)
• describe and comprehend bonding situations and other properties of organometallic compounds, including differences between main group and transition metal elements. (k2, k4)
• apply the knowledge to catalytic processes using transition metal compounds and assess possible modifications and improvements. (k3, k4, k5)
• design and describe synthetic procedures for organometallic compounds. (k6)
• understand and evaluate reaction mechanisms of transition metal compounds. (k2, k5)
• understand, analyze and assess the implementation of sustainability and green chemistry in the context of catalysis and chemical synthesis and production (k2, k3)
|
(*)• History of transition metal chemistry
• Basic and advanced bonding concepts
• Properties of transition metal complexes and compounds
• Homogeneous und heterogeneous catalysis
• Isolobal concept
• Dewar-Chatt-Duncanson bonding concept
• Synthesis planning
• Reaction mechanisms for organometallic compounds
• Industrial catalysis
• Synthetic chemistry
• Bioorganometallic chemistry
• Discussion of most important ligand classes: carbonyls, phosphines, cyclopentadienyl, etc.
|
|
| Beurteilungskriterien |
(*)Written exam at the end of the semester
|
| Lehrmethoden |
(*)Power point presentation
Additional explanations at the blackboard
|
| Abhaltungssprache |
Englisch |
| Literatur |
(*)- Organotransition Metal Chemistry: From Bonding to Catalysis, J. Hartwig, University Science Books, Sausalito, 2009
- The Organometallic Chemistry of the Transition Metals (6th Edition), R. H. Crabtree, Wiley, 2014
- Organometallic Chemistry (3rd Edition), G. O. Spessard, G. L. Miessler, Oxford University Press, 2015
- Introductory: Organometallics and Catalysis, M. Bochmann, Oxford University Press, 2015
|
| Lehrinhalte wechselnd? |
Nein |
| Frühere Varianten |
Decken ebenfalls die Anforderungen des Curriculums ab (von - bis)
491WANCOUMV16: VL Organometallchemie der Übergangsmetalle (2016W-2019S)
|
|
